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Linking renewables and fossil fuels with carbon capture via energy storage for a sustainable energy future

Dawid P. Hanak, Vasilije Manovic

《化学科学与工程前沿(英文)》 2020年 第14卷 第3期   页码 453-459 doi: 10.1007/s11705-019-1892-2

摘要: Renewable energy sources and low-carbon power generation systems with carbon capture and storage (CCS) are expected to be key contributors towards the decarbonisation of the energy sector and to ensure sustainable energy supply in the future. However, the variable nature of wind and solar power generation systems may affect the operation of the electricity system grid. Deployment of energy storage is expected to increase grid stability and renewable energy utilisation. The power sector of the future, therefore, needs to seek a synergy between renewable energy sources and low-carbon fossil fuel power generation. This can be achieved via wide deployment of CCS linked with energy storage. Interestingly, recent progress in both the CCS and energy storage fields reveals that technologies such as calcium looping are technically viable and promising options in both cases. Novel integrated systems can be achieved by integrating these applications into CCS with inherent energy storage capacity, as well as linking other CCS technologies with renewable energy sources via energy storage technologies, which will maximise the profit from electricity production, mitigate efficiency and economic penalties related to CCS, and improve renewable energy utilisation.

关键词: carbon capture     energy storage     renewable energy sources     decarbonisation     fossil fuels    

China’s policy framework for carbon capture, utilization and storage: Review, analysis, and outlook

《能源前沿(英文)》 2023年 第17卷 第3期   页码 400-411 doi: 10.1007/s11708-023-0862-z

摘要: Carbon capture, utilization, and storage (CCUS) is estimated to contribute substantial CO2 emission reduction to carbon neutrality in China. There is yet a large gap between such enormous demand and the current capacity, and thus a sound enabling environment with sufficient policy support is imperative for CCUS development. This study reviewed 59 CCUS-related policy documents issued by the Chinese government as of July 2022, and found that a supporting policy framework for CCUS is taking embryonic form in China. More than ten departments of the central government have involved CCUS in their policies, of which the State Council, the National Development and Reform Commission (NDRC), the Ministry of Science and Technology (MOST), and the Ministry of Ecological Environment (MEE) have given the greatest attention with different focuses. Specific policy terms are further analyzed following the method of content analysis and categorized into supply-, environment- and demand-type policies. The results indicate that supply-type policies are unbalanced in policy objectives, as policy terms on technology research and demonstration greatly outnumber those on other objectives, and the attention to weak links and industrial sectors is far from sufficient. Environment-type policies, especially legislations, standards, and incentives, are inadequate in pertinence and operability. Demand-type policies are absent in the current policy system but is essential to drive the demand for the CCUS technology in domestic and foreign markets. To meet the reduction demand of China’s carbon neutral goal, policies need to be tailored according to needs of each specific technology and implemented in an orderly manner with well-balanced use on multiple objectives.

关键词: carbon capture     utilization     and storage (CCUS)     policy     content analysis     China    

Lifecycle carbon footprint and cost assessment for coal-to-liquid coupled with carbon capture, storage

《能源前沿(英文)》 2023年 第17卷 第3期   页码 412-427 doi: 10.1007/s11708-023-0879-3

摘要: The coal-to-liquid coupled with carbon capture, utilization, and storage technology has the potential to reduce CO2 emissions, but its carbon footprint and cost assessment are still insufficient. In this paper, coal mining to oil production is taken as a life cycle to evaluate the carbon footprint and levelized costs of direct-coal-to-liquid and indirect-coal-to-liquid coupled with the carbon capture utilization and storage technology under three scenarios: non capture, process capture, process and public capture throughout the life cycle. The results show that, first, the coupling carbon capture utilization and storage technology can reduce CO2 footprint by 28%–57% from 5.91 t CO2/t·oil of direct-coal-to-liquid and 24%–49% from 7.10 t CO2/t·oil of indirect-coal-to-liquid. Next, the levelized cost of direct-coal-to-liquid is 648–1027 $/t of oil, whereas that of indirect-coal-to-liquid is 653–1065 $/t of oil. When coupled with the carbon capture utilization and storage technology, the levelized cost of direct-coal-to-liquid is 285–1364 $/t of oil, compared to 1101–9793 $/t of oil for indirect-coal-to-liquid. Finally, sensitivity analysis shows that CO2 transportation distance has the greatest impact on carbon footprint, while coal price and initial investment cost significantly affect the levelized cost of coal-to-liquid.

关键词: coal-to-liquid     carbon capture     utilization and storage (CCUS)     carbon footprint     levelized cost of liquid     lifecycle assessment    

Application of membrane separation technology in post-combustion carbon dioxide capture process

Mo LI,Xiaobin JIANG,Gaohong HE

《化学科学与工程前沿(英文)》 2014年 第8卷 第2期   页码 233-239 doi: 10.1007/s11705-014-1408-z

摘要: Membrane separation technology is a possible breakthrough in post-combustion carbon dioxide capture process. This review first focuses on the requirements for CO separation membrane, and then outlines the existing competitive materials, promising preparation methods and processes to achieve desirable CO selectivity and permeability. A particular emphasis is addressed on polyimides, poly (ethylene oxide), mixed-matrix membrane, thermally-rearranged polymer, fixed site carrier membrane, ionic liquid membrane and electrodialysis process. The advantages and drawbacks of each of materials and methods are discussed. Research threads and methodology of CO separation membrane and the key issue in this area are concluded

关键词: membranes     carbon dioxide capture     separation     polymers     post-combustion    

Review of solvent based carbon-dioxide capture technologies

Kathryn A. MUMFORD,Yue WU,Kathryn H. SMITH,Geoffrey W. STEVENS

《化学科学与工程前沿(英文)》 2015年 第9卷 第2期   页码 125-141 doi: 10.1007/s11705-015-1514-6

摘要: Currently, a large proportion of global fossil fuel emissions originate from large point sources such as power generation or industrial processes. This trend is expected to continue until the year 2030 and beyond. Carbon capture and storage (CCS), a straightforward and effective carbon reduction approach, will play a significant role in reducing emissions from these sources into the future if atmospheric carbon dioxide (CO ) emissions are to be stabilized and global warming limited below a threshold of 2 °C. This review provides an update on the status of large scale integrated CCS technologies using solvent absorption for CO capture and provides an insight into the development of new solvents, including advanced amine solvents, amino acid salts, carbonate systems, aqueous ammonia, immiscible liquids and ionic liquids. These proposed new solvents aim to reduce the overall cost CO capture by improving the CO absorption rate, CO capture capacity, thereby reducing equipment size and decreasing the energy required for solvent regeneration.

关键词: large scale     carbon dioxide     carbon capture     solvent absorption    

A coal-fired power plant integrated with biomass co-firing and CO capture for zero carbon emission

《能源前沿(英文)》 2022年 第16卷 第2期   页码 307-320 doi: 10.1007/s11708-021-0790-8

摘要: A promising scheme for coal-fired power plants in which biomass co-firing and carbon dioxide capture technologies are adopted and the low-temperature waste heat from the CO2 capture process is recycled to heat the condensed water to achieve zero carbon emission is proposed in this paper. Based on a 660 MW supercritical coal-fired power plant, the thermal performance, emission performance, and economic performance of the proposed scheme are evaluated. In addition, a sensitivity analysis is conducted to show the effects of several key parameters on the performance of the proposed system. The results show that when the biomass mass mixing ratio is 15.40% and the CO2 capture rate is 90%, the CO2 emission of the coal-fired power plant can reach zero, indicating that the technical route proposed in this paper can indeed achieve zero carbon emission in coal-fired power plants. The net thermal efficiency decreases by 10.31%, due to the huge energy consumption of the CO2 capture unit. Besides, the cost of electricity (COE) and the cost of CO2 avoided (COA) of the proposed system are 80.37 $/MWh and 41.63 $/tCO2, respectively. The sensitivity analysis demonstrates that with the energy consumption of the reboiler decreasing from 3.22 GJ/tCO2 to 2.40 GJ/ tCO2, the efficiency penalty is reduced to 8.67%. This paper may provide reference for promoting the early realization of carbon neutrality in the power generation industry.

关键词: coal-fired power plant     biomass co-firing     CO2 capture     zero carbon emission     performance evaluation    

Activated carbons and amine-modified materials for carbon dioxide capture –– a review

Zhenhe CHEN, Shubo DENG, Haoran WEI, Bin WANG, Jun HUANG, Gang YU

《环境科学与工程前沿(英文)》 2013年 第7卷 第3期   页码 326-340 doi: 10.1007/s11783-013-0510-7

摘要: Rapidly increasing concentration of CO in the atmosphere has drawn more and more attention in recent years, and adsorption has been considered as an effective technology for CO capture from the anthropogenic sources. In this paper, the attractive adsorbents including activated carbons and amine-modified materials were mainly reviewed and discussed with particular attention on progress in the adsorbent preparation and CO adsorption capacity. Carbon materials can be prepared from different precursors including fossil fuels, biomass and resins using the carbonization-activation or only activation process, and activated carbons prepared by KOH activation with high CO adsorbed amount were reviewed in the preparation, adsorption capacity as well as the relationship between the pore characteristics and CO adsorption. For the amine-modified materials, the physical impregnation and chemical graft of polyethylenimine (PEI) on the different porous materials were introduced in terms of preparation method and adsorption performance as well as their advantages and disadvantages for CO adsorption. In the last section, the issues and prospect of solid adsorbents for CO adsorption were summarized, and it is expected that this review will be helpful for the fundamental studies and industrial applications of activated carbons and amine-modified adsorbents for CO capture.

关键词: adsorption capacity     CO2 capture     activated carbon     amine-impregnated adsorbents    

An adaptive policy-based framework for China’s Carbon Capture and Storage development

Xiaoliang YANG, Wolfgang HEIDUG, Douglas COOKE

《工程管理前沿(英文)》 2019年 第6卷 第1期   页码 78-86 doi: 10.1007/s42524-019-0003-x

摘要:

China’s political leadership has taken an increasingly public and proactive stance on climate change since 2014. This stance includes making a commitment that Chinese carbon dioxide (CO2) emissions will peak around 2030 and enacting measures through the 13th Five-Year Plan to support energy efficiency, clean energy technology, and carbon management. Chinese policymakers consider carbon capture and storage (CCS) a critical bridging technology to help accelerate the decarbonization of its economy. This paper reviews and analyzes Chinese CCS support policies from the perspective of an adaptive policymaking framework, recognizing uncertainty as an inherent element of the policymaking process and drawing general lessons for responding to changing circumstances. Notably, the political support for CCS in China remains fragmented with uncoordinated government leadership, undecided industry players, and even with opposing voices from some leading scientists. There is scope for expanding the framework to provide more granularity, in particular relating to the development of a CCS infrastructure and the development of storage-focused CO2-EOR. Overall, given the role CCS can play to decarbonize China’s power and other industrial sectors, a commitment to CCS from top policymakers and major stakeholders is needed.

关键词: CCS     policy     climate change     China    

CCS,CCUS,CCRS,CMC系统集成

金涌,朱兵,胡山鹰,洪丽云

《中国工程科学》 2010年 第12卷 第8期   页码 49-55

摘要:

二氧化碳捕集—封存、生产生活中的节能减排和可再生能源的开发是实施低碳经济的三个核心举措。近年来提出的碳捕集—利用—封存和碳捕集—再利用—封存是更为积极的CO2减排应对策略。人类在未来必须要把宝贵的碳元素同时作为资源和能源载体循环利用,进行全程管理。

关键词: 低碳经济     碳捕集—封存     碳捕集—利用—封存     碳捕集—再利用—封存     碳的全程管理    

Carbon capture for decarbonisation of energy-intensive industries: a comparative review of techno-economic

《化学科学与工程前沿(英文)》 2022年 第16卷 第9期   页码 1291-1317 doi: 10.1007/s11705-022-2151-5

摘要: Carbon capture and storage will play a crucial role in industrial decarbonisation. However, the current literature presents a large variability in the techno-economic feasibility of CO2 capture technologies. Consequently, reliable pathways for carbon capture deployment in energy-intensive industries are still missing. This work provides a comprehensive review of the state-of-the-art CO2 capture technologies for decarbonisation of the iron and steel, cement, petroleum refining, and pulp and paper industries. Amine scrubbing was shown to be the least feasible option, resulting in the average avoided CO2 cost of between 62.7 €·tCO21 for the pulp and paper and 104.6 €·tCO21 for the iron and steel industry. Its average equivalent energy requirement varied between 2.7 (iron and steel) and 5.1 MJthkgCO21 (cement). Retrofits of emerging calcium looping were shown to improve the overall viability of CO2 capture for industrial decarbonisation. Calcium looping was shown to result in the average avoided CO2 cost of between 32.7 (iron and steel) and 42.9 €·tCO21 (cement). Its average equivalent energy requirement varied between 2.0 (iron and steel) and 3.7 MJthkgCO21 (pulp and paper). Such performance demonstrated the superiority of calcium looping for industrial decarbonisation. Further work should focus on standardising the techno-economic assessment of technologies for industrial decarbonisation.

关键词: industrial CO2 emissions     CCS deployment     carbonate looping     net-zero industry     carbon capture benchmarks    

Theoretical and experimental study on the fluidity performance of hard-to-fluidize carbon nanotubes-basedCO2 capture sorbents

《化学科学与工程前沿(英文)》 2022年 第16卷 第10期   页码 1460-1475 doi: 10.1007/s11705-022-2159-x

摘要: Carbon nanotubes-based materials have been identified as promising sorbents for efficient CO2 capture in fluidized beds, suffering from insufficient contact with CO2 for the high-level CO2 capture capacity. This study focuses on promoting the fluidizability of hard-to-fluidize pure and synthesized silica-coated amine-functionalized carbon nanotubes. The novel synthesized sorbent presents a superior sorption capacity of about 25 times higher than pure carbon nanotubes during 5 consecutive adsorption/regeneration cycles. The low-cost fluidizable-SiO2 nanoparticles are used as assistant material to improve the fluidity of carbon nanotubes-based sorbents. Results reveal that a minimum amount of 7.5 and 5 wt% SiO2 nanoparticles are required to achieve an agglomerate particulate fluidization behavior for pure and synthesized carbon nanotubes, respectively. Pure carbon nanotubes + 7.5 wt% SiO2 and synthesized carbon nanotubes + 5 wt% SiO2 indicates an agglomerate particulate fluidization characteristic, including the high-level bed expansion ratio, low minimum fluidization velocity (1.5 and 1.6 cm·s–1), high Richardson−Zakin index (5.2 and 5.3 > 5), and low Π value (83.2 and 84.8 < 100, respectively). Chemical modification of carbon nanotubes causes not only enhanced CO 2 uptake capacity but also decreases the required amount of silica additive to reach a homogeneous fluidization behavior for synthesized carbon nanotubes sorbent.

关键词: CO2 capture     CNT-based sorbents     fluidization     SiO2 nanoparticles     fluidized bed reactors    

Achievements, challenges and global implications of China’s carbon neutral pledge

《环境科学与工程前沿(英文)》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1532-9

摘要: China has been committed to achieving carbon neutrality by 2060. China’s pledge of carbon neutrality will play an essential role in galvanising global climate action, which has been largely deferred by the Covid-19 pandemic. China’s carbon neutrality could reduce global warming by approximately 0.2–0.3 °C and save around 1.8 million people from premature death due to air pollution. Along with domestic benefits, China’s pledge of carbon neutrality is a “game-changer” for global climate action and can inspire other large carbon emitters to contribute actively to mitigate carbon emissions, particularly countries along the Belt and Road Initiative (BRI) routes. In order to achieve carbon neutrality by 2060, it is necessary to decarbonise all sectors in China, including energy, industry, transportation, construction, and agriculture. However, this transition will be very challenging, because major technological breakthroughs and large-scale investments are required. Strong policies and implementation plans are essential, including sustainable demand, decarbonizing electricity, electrification, fuel switching, and negative emissions. In particular, if China can peak carbon emissions earlier, it can lower the costs of the carbon neutral transition and make it easier to do so over a longer time horizon. China’s pledge of carbon neutrality by 2060 and recent pledges at the 26th UN Climate Change Conference of the Parties (COP26) are significant contributions and critical steps for global climate action. However, countries worldwide need to achieve carbon neutrality to keep the global temperature from growing beyond the level that will cause catastrophic damages globally.

关键词: Carbon neutrality     Carbon peak     Renewable energy     Negative emission     Carbon capture     Utilisation and storage     Nature-based solution    

Assessment of postcombustion carbon capture technologies for power generation

Mikel C. DUKE, Bradley LADEWIG, Simon SMART, Victor RUDOLPH, João C. Diniz da COSTA,

《化学科学与工程前沿(英文)》 2010年 第4卷 第2期   页码 184-195 doi: 10.1007/s11705-009-0234-1

摘要: A significant proportion of power generation stems from coal-combustion processes and accordingly represents one of the largest point sources of CO emissions worldwide. Coal power plants are major assets with large infrastructure and engineering units and an operating life span of up to 50 years. Hence, any process design modification to reduce greenhouse gas emissions may require significant investment. One of the best options to utilize existing infrastructure is to retrofit the power station fleet by adding a separation process to the flue gas, a practice known as postcombustion capture (PCC). This review examines the recent PCC development and provides a summary and assessment of the state of play in this area and its potential applicability to the power generation industry. The major players including the various institutes, government, and industry consortia are identified along with flue gas PCC demonstration scale plants. Of the PCC technologies reviewed, amine-based absorption is preeminent, being both the most mature and able to be adapted immediately, to the appropriate scale, for power station flue gas with minimal technical risk. Indeed, current commercial applications serve niches in the merchant CO market, while a substantial number of smaller scale test facilities are reported in the literature with actual CO capture motivated demonstrations now commencing. Hybrid membrane/absorption systems, also known as membrane contactors, offer the potential for the lowest energy requirements, possibly 10% of current direct scrubbers but are at an early stage of development. Other methods being actively pursued as R&D projects include solid absorbents, solid adsorbents, gas membrane separators, and cryogenic separation. The variety and different maturities of these competing technologies make technical comparison largely subjective, but useful insights could be gained through the development and application of econometric techniques such as ‘real options’ within this context. Despite these limitations, it is clear from this review that amine scrubbing is likely to be adapted first into the existing power station fleet, while less mature technologies will grow and become integrated with the development of future power stations.

单乙醇胺碳捕集工艺大规模工业化应用:提高非平衡级速率模型的预测精度

罗小波,Wang Meihong

《工程(英文)》 2017年 第3卷 第2期   页码 232-243 doi: 10.1016/J.ENG.2017.02.001

摘要:

对于减少化石能源发电厂和其他能源密集型过程的人为二氧化碳(CO2) 的排放,碳捕集和储存(CCS)技术将发挥至关重要的作用。然而, 由于装备CO2捕集装置而导致的成本增加是其大规模工业化应用的主要障碍。为减少碳捕集装置的一次性投资费用和后续操作费用,大量的研究通过流程建模、仿真和优化来实现该过程的优化设计和优化操作。为此,准确的模型是必不可少的基础。本文论述了关于通过升级参数和多级模型验证来开发一个更精确的基于乙醇胺碳捕集过程的非平衡级速率模型。本文首先分析了该过程速率模型的建模框架。采用Aspen Plus® 软件开发此过程的稳态模型,并且在三个模拟阶段对较宽范围的压力,温度和CO2 载荷进行了模型验证,包括热力学建模、物性计算和中试规模工艺模拟。采用在Aspen Plus® 中编写Fortran 子程序升级了液相密度和气液相接触面积计算的关联参数。模型验证结果表明,本文中采用的新的关联参数组合的热力学模型比其他三个经典模型具有更高的精度,而且试验规模的流程模拟结果和实验数据吻合很好。随后本文采用这一模型对一个250 MW 的联合循环燃气发电厂的碳捕集工艺过程设计进行了案例研究,并和另一文献进行了对比,本文的设计降低了吸收塔和解析塔的填料高度并减少了CO2特征热负荷。

关键词: 过程模拟     模型验证     单乙醇胺     CO2 捕集     联合燃气发电厂     碳捕集和存储    

The capture of carbon dioxide by transition metal aluminates, calcium aluminate, calcium zirconate, calcium

Ganesh TILEKAR, Kiran SHINDE, Kishor KALE, Reshma RASKAR, Abaji GAIKWAD

《化学科学与工程前沿(英文)》 2011年 第5卷 第4期   页码 477-491 doi: 10.1007/s11705-011-1107-y

摘要: The capture of CO by transition metal (Mn, Ni, Co and Zn) aluminates, calcium aluminate, calcium zirconate, calcium silicate and lithium zirconate was carried out at pre- and post-combustion temperatures. The prepared metal adsorbents were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), surface area analysis and acidity/alkalinity measurements. The different experimental variables affecting the adsorbents ability to capture CO , such as the mol ratio of metal ions, the pressure of CO , the exposure time and the temperature of the adsorbent were also investigated. Calcium zirconate captured 13.85 wt-% CO at 650°C and 2.5 atm and calcium silicate captured 14.31 wt-% at 650°C. Molecular sieves (13X) and carbon can only capture a negligible amount of CO at high temperatures (300°C–650°C). However, the mixed metal oxides captured reasonable amount of CO at these higher temperatures. In addition, calcium aluminate, calcium zirconate, calcium silicate and lithium zirconate adsorbents captured CO at both pre and post-combustion temperatures. The trend for the amount of captured carbon dioxide over the adsorbents was calcium aluminate

关键词: captured CO2     pre-combustion temperature     characterization     calcium silicate     calcium zirconate    

标题 作者 时间 类型 操作

Linking renewables and fossil fuels with carbon capture via energy storage for a sustainable energy future

Dawid P. Hanak, Vasilije Manovic

期刊论文

China’s policy framework for carbon capture, utilization and storage: Review, analysis, and outlook

期刊论文

Lifecycle carbon footprint and cost assessment for coal-to-liquid coupled with carbon capture, storage

期刊论文

Application of membrane separation technology in post-combustion carbon dioxide capture process

Mo LI,Xiaobin JIANG,Gaohong HE

期刊论文

Review of solvent based carbon-dioxide capture technologies

Kathryn A. MUMFORD,Yue WU,Kathryn H. SMITH,Geoffrey W. STEVENS

期刊论文

A coal-fired power plant integrated with biomass co-firing and CO capture for zero carbon emission

期刊论文

Activated carbons and amine-modified materials for carbon dioxide capture –– a review

Zhenhe CHEN, Shubo DENG, Haoran WEI, Bin WANG, Jun HUANG, Gang YU

期刊论文

An adaptive policy-based framework for China’s Carbon Capture and Storage development

Xiaoliang YANG, Wolfgang HEIDUG, Douglas COOKE

期刊论文

CCS,CCUS,CCRS,CMC系统集成

金涌,朱兵,胡山鹰,洪丽云

期刊论文

Carbon capture for decarbonisation of energy-intensive industries: a comparative review of techno-economic

期刊论文

Theoretical and experimental study on the fluidity performance of hard-to-fluidize carbon nanotubes-basedCO2 capture sorbents

期刊论文

Achievements, challenges and global implications of China’s carbon neutral pledge

期刊论文

Assessment of postcombustion carbon capture technologies for power generation

Mikel C. DUKE, Bradley LADEWIG, Simon SMART, Victor RUDOLPH, João C. Diniz da COSTA,

期刊论文

单乙醇胺碳捕集工艺大规模工业化应用:提高非平衡级速率模型的预测精度

罗小波,Wang Meihong

期刊论文

The capture of carbon dioxide by transition metal aluminates, calcium aluminate, calcium zirconate, calcium

Ganesh TILEKAR, Kiran SHINDE, Kishor KALE, Reshma RASKAR, Abaji GAIKWAD

期刊论文